Logo der Universität Wien

Toward the synthesis of the antibiotic branimycin: novel approaches to highly substituted cis-decalin systems

Mulzer, Johann; Castagnolo, Daniele; Felzmann, Wolfgang; Marchart, Stefan; Pilger, Christian; Enev, Valentin S.   

Chemistry--A European Journal  (2006),  12(23),  5992-6001.

A variety of highly functionalized cis-decalin systems have been prepared by means of the stereoselective transannular Diels-Alder (TADA) reaction of a (Z,E,Z,Z)-tetraene macrolide, and by means of intramolecular nitrile oxide olefin (INOC) or ring-closing metathesis (RCM) annulations to quinic acid derivatives.

 

Johann Mulzer
Institute for Organic Chemistry
University of Vienna

Währingerstraße 38
A-1090 Vienna

University of Vienna | Universitätsring 1 | 1010 Vienna | T +43-1-4277-0